• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    A method for minimizing the amount of nitrogen oxide pollutants produced in a process for firing a furnace using oxygen or an oxygen-enriched gas as the oxidant, in which furnace gases are aspirated into the oxidant jet prior to combustion and in which the furnace is operated using alternating low firing rate and high firing rate periods, by delaying the injection of oxidant at the high rate at the start of the high firing rate period.
    公开号:SU1407403A3
    申请号:SU833532553
    申请日:1983-01-05
    公开日:1988-06-30
    发明作者:Кобаяси Хисаси；Андерсон Эрлинг
    申请人:Юнион Карбид Корпорейшн (Фирма)；
    IPC主号:
    专利说明:

    The invention relates to ferrous metallurgy, and more specifically to a method of furnace heating, in which oxygen or oxygen-enriched air is used as an oxidizer, and the operation of the furnace is characterized by the presence of low and high heat loads.
    I The purpose of the invention is to reduce nitrogen oxides.
    The essence of the proposed method of heating the furnace consists in burning fuel and gaseous oxidizer with the formation of furnace gases, in which at least one jet of gaseous oxidant selected from | the group comprising air and oxygen enriched with kyphod and, at least one stream of fuel is blown into the kiln, as a result of which the kiln gases are absorbed by the oxide before the combustion .. Heating the kiln to maintain the temperature range, including The set temperature is produced using a series of high and low heat loads. A period of low heat load is characterized by blowing into the fuel and oxidizer furnace at such feed rates that a significant leak of air into the net occurs. And the period of high heat load following it is characterized by injection of fuel and oxidant into the furnace at feed rates that are higher than the corresponding feed rates during the period of low heat load, which leads to a slight leakage of air into the oven, or such leakage does not occur at all. When this is achieved, a reduction in NOj distributions is achieved, based on the delay of blowing the oxidant at the beginning of the high heat load period, but not a finite period of time (the fever sys tem S which is derived from
    iJ 4.12-10 V / fT,
    rjE (6 S V
    delay time, s; furnace volume, f - heat load during the period of high heat load, kcal / s; T is given, temperature, K. The term oxygen-enriched air is used to define
    0
    air, the oxygen content in which exceeds the natural oxygen content,
    Figure 1 shows schematically the furnace used to carry out the proposed method, top view; figure 2 is the same, side view; in figs. 3 and 4, the graphical depiction has made the scientific research institute NOj, depending on time, obtained in examples 1 and 2, respectively.
    When a furnace that uses oxygen as an oxidizing agent or oxygen enriched with oxygen is such that the furnace gases are absorbed by the oxidizing agent prior to combustion and alternating periods of high and low heat load are used, a significant reduction in NOjj emissions is achieved during the period of high heat load if the increase in the oxidant feed rate is delayed for a finite period of time after the start of the period of high heat load; moreover, such a delay period does not exceed a period of time 5.
    The delay time is finite, i.e. always greater than zero. However, there is no absolute lower period, so some reduction in the formation of N0 will be observed even at small time delays, for example, 1 s. In most cases, the time delay is 0.1-0.8 S, and mostly 0.3-0.7 S. It has been established that when using this method, the time delay is 5-10 sec.
    Although the oxidizer feed rates during the delay are less than the feed rate during the high heat load period, they should not be zero or equal to the feed rate during the low heat load period. The oxidant feed rate during the delay can be about the same as during the low heat load period.
    0 during operation of the furnace, the furnace gases are removed from the furnace, for example, through a pipe and around the furnace hatches. While the furnace is operating at a high heat load, the speed is high.
    5, the supply of fuel and oxidant to the furnace to achieve a high heat load is sufficient to replace furnace gases that are removed from
    0
    five
    0
    five
    ovens. Thus, there is a slight leakage of air into the furnace, or there is no such leakage at all. However, during the period of operation of the furnace with a low heat load, the lower feed rate of the fuel and oxidant to the furnace is insufficient to replace the furnace gases that are removed from the furnace. This leads to the creation of negative pressure inside the furnace and air leakage into the furnace through a series of holes.
    It is known that the formation of N0, t increases significantly at elevated temperatures. In carrying out the process, when the furnace gases, which are usually carbon dioxide and water vapor, are sucked into the oxidant stream before combustion, the flame temperature is lower than usual due to the lower oxygen concentration resulting from the oxidizer diluting the furnace gases. This is lower compared to conventional flame temperatures leading to less N0 formation. However, when this method of heating the furnace is carried out using alternating periods of low and high heat loads, the furnace atmosphere at the end of the period of low heat loads is mainly air due to the previously considered leakage of air into the furnace. Therefore, during the period of high heat load, air is sucked into the jet of oxidizer instead of furnace gas, gas. This leads to a higher concentration of oxygen, which contributes to an increase in flame temperature and a higher amount of N0. The rate of formation of N0 is reduced by replacing the air in the furnace with furnace gases, since during the period of high load pressure no air leaks into the furnace.
    When, at the beginning of a high heat load period, the injection of an oxidizing agent with a feed rate characteristic of a high heat load is delayed for a short period of time, the fuel is initially burned with oxygen in the air inside the furnace. Due to the high fuel feed rate, this oxygen in the air is quickly depleted, and when the oxidant is blown into the furnace at a feed rate characteristic of high thermal load
    0
    five
    0
    five
    0
    five
    0
    five
    However, there is still little oxygen inside the furnace to suck in a stream of oxidant, or this oxygen is completely absent. Thus, the oxidizing agent is diluted without mixing with oxygen-containing air, as a result of which it is possible to avoid a high concentration of oxygen. This leads to a lower flame temperature and less formation of N0.
    Examples of the implementation of the proposed method.
    Experimental furnace 1 with a volume of 3.6 m operated with the use of a high heat load up to the achievement of a given high temperature. After that, alternating periods of high and low heat loads were applied. The fuel, which was natural gae, having a high calorific value of about 9000 kcal / m, was injected with a low feed rate characteristic of low thermal heating to the furnace 1 through the burner 2. A small amount of oxidant was also introduced through this burner. . Air was introduced into the furnace through the opening 3 in order to simulate the leakage of air into the furnace during the period of low heat load occurring in the industrial furnace. Gases were discharged through gas outlets 4, where they were analyzed for the content of N0.
    When the temperature reached the lower preset point, the furnace began to operate with a high heat load until the upper preset temperature point was reached. During the period of high heat load, no air was introduced into the furnace.
    Each example presented in the table was carried out in two stages. At the first stage, the oxidizer was introduced immediately after the beginning of the period of high heat load, i.e. without time delay. Thus, the first stage of each example illustrates the operation of the furnace without applying the proposed method. At the second stage, the oxidizer was introduced after a certain time delay (in example 1, the time delay was 7 seconds, and in example 2, 9.8 seconds. Thus, the second stage of each example illustrates the operation of the switch using the proposed method. In each example The oxidant used was technically pure oxygen.
    five
    The instantaneous N0 content in the exhaust gas in parts per million (ppm) is shown in graphical form in FIG. 3.4. FIG. Figure 3 illustrates the instantaneous concentration of NOy in the exhaust gas as a function of time, characteristic of Example 1. I The solid line represents the concentration of NOx in the first stage of Example 1 and the dotted line represents the concentration N0 in the second stage 2 of Example 1. In a similar way 4, an instantaneous concentration of NOx in the flue gas is characterized, characteristic for example 2, the solid one represents the first stage, and the dotted line represents the second
    stage of the example.
     I I
    The results of examples 1 and 2 are shown in the table.

    i As can be seen from the table and fig. 3.4, a significant reduction in the {ifOx formation is achieved as a result of applying the IIHH method of the invention (steps 2 of Examples 1 and 2) as compared to the well-known (steps 1 of examples 1 and 2). The invention allows you to reduce the formation of NOx by 40-53%.
    g
    0
    25 to
    权利要求:
    Claims (1)
    [1]
    6 claims
    The method of heating the furnace, including the separate supply to the furnace of fuel and gaseous oxidant, such as oxygen or oxygen-enriched air, burning fuel to form kiln gases, suction of kiln gases into gaseous oxidizer before burning, while heating the kiln is produced to a predetermined temperature alternating periods of and low heat loads with corresponding fuel and oxidant supply rates, which differ, in order to reduce the formation of nitrogen oxides, in a period of low heat loading 5.5 kcal / s additionally, air is supplied to the furnace as an oxidizing agent; during the period of high heat load 51-63 kcal / s, the supply of air to the furnace is stopped, and oxygen is supplied as an oxidizing agent with a time delay S equal to
    S 4.12 where s
    . V f
    10 V / ft,
    -Time of delay, s;
    - furnace volume, m;
    - heat load during the period of high heat load, kcal / s;
    - set temperature, K.
    Characteristic method
    Example 1 in step 2
    Fuel rate; during heat load:
    high 20,4 20,4
    low
    Oxidant feed rate, m / h, during heat load:
    high
    low
    Heat load, kcal / s:
    is high
    is low
    Air flow, m- / h
    U
    Required temperature, C
    Example 2 on stage

    25.2 2.2
    54.7 4.5
    63
    5.5 164 1260
    f.Z
    U07403
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    同族专利:
    公开号 | 公开日
    KR840002978A|1984-07-21|
    JPS64603B2|1989-01-09|
    US4408982A|1983-10-11|
    CA1183766A|1985-03-12|
    EP0083562B1|1986-11-26|
    BR8207511A|1983-10-18|
    ES518794A0|1984-01-16|
    ES8402412A1|1984-01-16|
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    MX157943A|1988-12-26|
    AU1008683A|1983-07-14|
    EP0083562A2|1983-07-13|
    KR880002466B1|1988-11-14|
    AU549110B2|1986-01-16|
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    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    US3699903A|1971-02-25|1972-10-24|Oliver F King|Method for improving fuel combustion in a furnace and for reducing pollutant emissions therefrom|
    US3730668A|1971-03-03|1973-05-01|Tokyo Gas Co Ltd|Combustion method of gas burners for suppressing the formation of nitrogen oxides and burner apparatus for practicing said method|
    GB1465785A|1973-03-12|1977-03-02|Tokyo Gas Co Ltd|Burner and method of combustion-|
    US3880571A|1973-07-26|1975-04-29|Trw Inc|Burner assembly for providing reduced emission of air pollutant|
    US4060376A|1974-12-11|1977-11-29|Energiagazdalkodasi Intezet|Method of firing and furnace therefor|
    US4054407A|1975-12-29|1977-10-18|Engelhard Minerals & Chemicals Corporation|Method of combusting nitrogen-containing fuels|
    JPS5812481B2|1976-03-01|1983-03-08|Hitachi Seisakusho Kk|
    JPS5723171B2|1977-10-22|1982-05-17|
    SE439980B|1978-06-02|1985-07-08|United Stirling Ab & Co|METHOD AND DEVICE FOR REGULATING AIR / FUEL MIXTURE BY BURNER OF THE TYPE DESIGNED WITH AN EVAPORATOR TUBE|
    US4261508A|1979-05-21|1981-04-14|The G. C. Broach Company|Combustion control system|
    US4343606A|1980-02-11|1982-08-10|Exxon Research & Engineering Co.|Multi-stage process for combusting fuels containing fixed-nitrogen chemical species|
    US4308810B1|1980-04-09|1993-08-03|Foster Wheeler Energy Corp|
    US4378205A|1980-04-10|1983-03-29|Union Carbide Corporation|Oxygen aspirator burner and process for firing a furnace|
    JPS572927A|1980-06-09|1982-01-08|Matsushita Electric Ind Co Ltd|Combustion apparatus|
    US4375950A|1981-04-01|1983-03-08|Durley Iii Benton A|Automatic combustion control method and apparatus|US4699586A|1986-05-16|1987-10-13|Union Carbide Corporation|Method for igniting a multiburner furnace|
    US4738614A|1986-07-25|1988-04-19|Union Carbide Corporation|Atomizer for post-mixed burner|
    US4846665A|1987-10-23|1989-07-11|Institute Of Gas Technology|Fuel combustion|
    US4863371A|1988-06-03|1989-09-05|Union Carbide Corporation|Low NOx high efficiency combustion process|
    US5213492A|1991-02-11|1993-05-25|Praxair Technology, Inc.|Combustion method for simultaneous control of nitrogen oxides and products of incomplete combustion|
    US5242295A|1991-02-11|1993-09-07|Praxair Technology, Inc.|Combustion method for simultaneous control of nitrogen oxides and products of incomplete combustion|
    US5076779A|1991-04-12|1991-12-31|Union Carbide Industrial Gases Technology Corporation|Segregated zoning combustion|
    US5263849A|1991-12-20|1993-11-23|Hauck Manufacturing Company|High velocity burner, system and method|
    US6702569B2|2001-01-11|2004-03-09|Praxair Technology, Inc.|Enhancing SNCR-aided combustion with oxygen addition|
    US20020127505A1|2001-01-11|2002-09-12|Hisashi Kobayashi|Oxygen enhanced low nox combustion|
    US6699031B2|2001-01-11|2004-03-02|Praxair Technology, Inc.|NOx reduction in combustion with concentrated coal streams and oxygen injection|
    US6699030B2|2001-01-11|2004-03-02|Praxair Technology, Inc.|Combustion in a multiburner furnace with selective flow of oxygen|
    US6699029B2|2001-01-11|2004-03-02|Praxair Technology, Inc.|Oxygen enhanced switching to combustion of lower rank fuels|
    US6978726B2|2002-05-15|2005-12-27|Praxair Technology, Inc.|Combustion with reduced carbon in the ash|
    ES2566798T3|2002-05-15|2016-04-15|Praxair Technology, Inc.|Combustion with low NOx emissions|
    US20040175663A1|2003-03-06|2004-09-09|M. Shannon Melton|Method for combusting fuel in a fired heater|
    US20070231761A1|2006-04-03|2007-10-04|Lee Rosen|Integration of oxy-fuel and air-fuel combustion|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    US06/337,115|US4408982A|1982-01-05|1982-01-05|Process for firing a furnace|
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